Ruthenium hydride catalyzed silylvinylation of terminal alkynes under ethylene atmosphere at 80 psi
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.09.023
Abstract: The development of methods for the stereoselective synthesis of polysubstituted 1,3-dienes is a challenge to synthetic chemistry. Herein is reported a selective approach for the synthesis of polysubstituted 1,3-dienes using the ruthenium hydride catalyzed intramolecular… read more here.
Keywords: catalyzed silylvinylation; ruthenium hydride; terminal alkynes; hydride catalyzed ... See more keywords
Zirconium-hydride-catalyzed site-selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and application
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Journal of Catalysis"
DOI: 10.1016/s1872-2067(21)63853-6
Abstract: Abstract Developing mild and efficient catalytic methods for the selective synthesis of amines is a longstanding research objective. In this respect, catalytic deoxygenative amide reduction has proven to be promising but challenging, as this approach… read more here.
Keywords: zirconium hydride; bond cleavage; hydride catalyzed; selective hydroboration ... See more keywords