Synthesis of Silyl Aluminum Reagents: Relevance Toward Atomic Layer Deposition of Metal Silicides and the Serendipitous Synthesis of a Novel Al-Hydride Cluster.
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DOI: 10.1021/acs.inorgchem.0c02730
Abstract: The novel mono-silyl [(R3Si)AlX2]2, di-silyl [(R3Si)2AlX]2, tri-silyl (R3Si)3Al·Et2O, and -ate-complex [(R3Si)4Al]-·Li+(Et2O)2 have been synthesized by reaction of AlX3 (X = Cl, Br) with silyl lithium reagents (tBuMe2SiLi, Et3SiLi) in Et2O. Treatment of these compounds with… read more here.
Keywords: silyl aluminum; hydride cluster; silyl; synthesis ... See more keywords