Electrocatalytic Proton Reduction by a Cobalt(III) Hydride Complex with Phosphinopyridine PN Ligands.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02505
Abstract: Cobalt complexes with 2-(diisopropylphosphinomethyl)pyridine (PN) ligands have been synthesized with the aim of demonstrating electrocatalytic proton reduction to dihydrogen with a well-defined hydride complex of an Earth-abundant metal. Reactions of simple cobalt precursors with 2-(diisopropylphosphino-methyl)pyridine… read more here.
Keywords: cobalt; proton reduction; electrocatalytic proton; proton ... See more keywords
Preparation, Characterization, and Electrochemical Activation of a Model [Cp*Rh] Hydride.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02160
Abstract: Monomeric half-sandwich rhodium hydride complexes are often proposed as intermediates in catalytic cycles, but relatively few such compounds have been isolated and studied, limiting understanding of their properties. Here, we report preparation and isolation of… read more here.
Keywords: hydride; characterization electrochemical; electrochemical activation; preparation characterization ... See more keywords
Hydroboration of CO2 catalyzed by heteroscorpionate zwitterionic zinc and magnesium hydride complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00279e
Abstract: The heteroscorpionate zinc hydride complex LZnH 2, (L = (MePz)2CP(Ph)2NPh, MePz = 3,5-dimethylpyrazolyl), its formate complex 3, and magnesium hydride complex LMgH 5 with the same ligand were synthesized and detected for the catalytic hydroboration… read more here.
Keywords: magnesium; zinc; hydroboration; hydride ... See more keywords
Visible light induced formation of a tungsten hydride complex.
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DOI: 10.1039/d2dt03675d
Abstract: When irradiated with blue light in the presence of a Lewis base (L), [CpW(CO)3]2 undergoes metal-metal bond cleavage followed by a disproportionation reaction to form [CpW(CO)3L]+ and [CpW(CO)3]-. Here, we show that in the presence… read more here.
Keywords: cpw; light induced; hydride; visible light ... See more keywords
Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex
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DOI: 10.3390/molecules27175553
Abstract: The side-on end-on dinitrogen hydride complex [{Na(dme)}2{(O3)Nb}2(μ-η1:η2-N2)(μ-H)2] (3-Na, [O3]3− = [(3,5-tBu2-2-O-C6H2)3CH]3−) was observed to undergo facile elimination of H2 and cleavage of the N–N bond in the presence of 9-borabicyclo[3.3.1]nonane (9-BBN), AlMe3, and ZnMe2. Treatment… read more here.
Keywords: dinitrogen; side end; cleavage; hydride complex ... See more keywords