Divalent Lanthanide Hydride Complexes
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400593
Abstract: Molecular hydride complexes have attracted recent attention, and divalent lanthanides as central atoms in particular are very interesting. They open up possibilities of combining hydride reactivity and lanthanide reactivity. To date, only Yb(II), Eu(II) and… read more here.
Keywords: lanthanide hydride; chemistry; hydride complexes; divalent lanthanide ... See more keywords
Transition metal hydride complexes as mechanistic models for proton reduction catalysis
Sign Up to like & getrecommendations! Published in 2018 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2018.02.014
Abstract: Abstract The paper presents a brief overview of the role of metal hydride complexes in understanding the dynamics of hydrogen generation in homogeneous water reduction catalysts. In addition, the kinetics of protonation of [Os(phen)2(CO)(H)]+ and… read more here.
Keywords: hydride complexes; reduction; transition metal; metal hydride ... See more keywords
Ligand acidity constants as calculated by density functional theory for PF3 and N-Heterocyclic carbene ligands in hydride complexes of Iron(II)
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.10.024
Abstract: Abstract The deprotonation of metal-hydride intermediates is a key step in some catalytic processes, making the pKa of these intermediates a notable characteristic in the design of catalysts. The acid dissociation constant (Ka) in THF… read more here.
Keywords: hydride complexes; ligand acidity; pf3; acidity constants ... See more keywords
Synthesis and Reactivity of Metal–Ligand Cooperative Bifunctional Ruthenium Hydride Complexes: Active Catalysts for β-Alkylation of Secondary Alcohols with Primary Alcohols
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00432
Abstract: Three unsymmetrical NNN ligands with a 2-hydroxypyridyl fragment were used to react with RuHCl(PPh3)3(CO), affording the three bidentate ruthenium hydride complexes [(R1-C5H3N-CH2-C5H3N-C5H3N-R2)Ru... read more here.
Keywords: hydride complexes; ruthenium hydride; synthesis reactivity; reactivity metal ... See more keywords
A series of neutral alkaline earth metal hydride complexes supported by a bulky, unsymmetrical β-diketiminate ligand, [{(Dip/TCHPNacnac)M(μ-H)}2] (M = Mg, Ca, Sr or Ba).
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc04286g
Abstract: A bulky, unsymmetrical β-diketiminate ligand, [HC{MeCN(Dip)}{MeCN(TCHP)}]- (Dip/TCHPNacnac; Dip = 2,6-diisopropylphenyl, TCHP = 2,4,6-tricyclohexylphenyl), has been utilised in the preparation of a series of magnesium alkyl and calcium, strontium and barium amide complexes. Reaction of these… read more here.
Keywords: dip; hydride complexes; diketiminate ligand; dip tchpnacnac ... See more keywords
Acceptorless oxidant-free dehydrogenation of amines catalyzed by Ru-hydride complexes of amide-acid/ester ligands.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d4dt03201b
Abstract: Traditional dehydrogenation of amines involves the transfer of hydrogen molecule(s) from a substrate to an acceptor. In acceptorless dehydrogenation, hydrogen gas is liberated without an oxidant, providing an efficient synthetic method. Acceptorless dehydrogenation of primary… read more here.
Keywords: hydride complexes; complexes amide; dehydrogenation; amide acid ... See more keywords
Bimetallic Zr,Zr-Hydride Complexes in Zirconocene Catalyzed Alkene Dimerization
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25092216
Abstract: Being valuable precursors in the production of adhesives, lubricants, and other high-performance synthetic compounds, alkene dimers and oligomers can be obtained using homogeneous zirconocene catalytic systems. Further advances in such systems require precise control of… read more here.
Keywords: complexes zirconocene; hydride; alkene dimerization; bimetallic hydride ... See more keywords