Synthesis, Structure, and Reactivity of a Terminal Cadmium Hydride Compound, [κ3-TismPriBenz]CdH.
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DOI: 10.1021/jacs.1c04987
Abstract: The terminal cadmium hydride compound, [κ3-TismPriBenz]CdH, which features the tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl ligand, may be obtained via the reactions of either [κ3-TismPriBenz]CdN(SiMe3)2 or [TismPriBenz]CdOSiPh3 with PhSiH3. The Cd-H bond of [κ3-TismPriBenz]CdH undergoes (a) metathesis reactions with MeI,… read more here.
Keywords: hydride compound; terminal cadmium; tismpribenz; tismpribenz cdh ... See more keywords
Catalytic reduction of carbon dioxide by a zinc hydride compound, [Tptm]ZnH, and conversion to the methanol level.
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DOI: 10.1039/d1dt04156h
Abstract: The zinc hydride compound, [Tptm]ZnH, may achieve the reduction of CO2 by (RO)3SiH (R = Me, Et) to the methanol oxidation level, (MeO)xSi(OR)4-x, via the formate species, HCO2Si(OR)3. However, because insertion of CO2 into the… read more here.
Keywords: hydride compound; methanol level; compound tptm; level ... See more keywords