Synthesis of Trimetallic (HPd@M2Au8)3+ Superatoms (M = Ag, Cu) via Hydride-Mediated Regioselective Doping to (Pd@Au8)2+
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DOI: 10.1021/acsomega.9b00575
Abstract: We have recently reported that hydride (H–) doped superatom (HPd@Au8)+ protected by eight PPh3 ligands selectively grew into (HPd@Au10)3+ by the nucleophilic addition of two Au(I)Cl units. In the present study, (HPd@Au8)+ was successfully converted… read more here.
Keywords: m2au8 superatoms; hydride mediated; hpd m2au8; trimetallic hpd ... See more keywords
Solvent basicity promotes the hydride-mediated electron transfer doping of carbon nanotubes.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc04295g
Abstract: This study investigates the hydride-mediated electron transfer doping of single-walled carbon nanotubes using absorption spectroscopy and thermoelectric measurements. Specific solvent basicity is found to be important for the efficient n-type doping of carbon nanotubes. This… read more here.
Keywords: hydride mediated; carbon; transfer doping; electron transfer ... See more keywords