Dehydration of primary amides to nitriles catalyzed by [CNC]-pincer hydrido cobalt(III) complexes
Sign Up to like & getrecommendations! Published in 2019 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2018.12.002
Abstract: Abstract The dehydration reactions from primary amides to nitriles were catalyzed by the [CNC]-pincer hydrido cobalt(III) complexes [(ortho-F4C6 CH N C10H6)Co(III)(H)(PMe3)2] (1), [(2,5-F2C6H2 CH N C10H6)Co(III)(H)(PMe3)2] (2) and [(2,4,5-F3C6H CH N C10H6)Co(III)(H)(PMe3)2] (3) as catalysts… read more here.
Keywords: iii; amides nitriles; hydrido cobalt; cobalt iii ... See more keywords
Hydrido-Cobalt Complexes for the Chemo- and Regioselective 1,2-Silylative Dearomatization of N-Heteroarenes.
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DOI: 10.1021/acs.orglett.3c00022
Abstract: We describe an efficient regio- and chemoselective dearomatization of N-heteroarenes using hydrido-cobalt catalysts. Reactions were performed under mild conditions on a wide range of N-heteroarenes leading exclusively to the silyl-1,2-dihydroheteroarene. Various quinolines and pyridines bearing… read more here.
Keywords: complexes chemo; dearomatization heteroarenes; hydrido cobalt; cobalt complexes ... See more keywords