A (μ-hydrido)diborane(4) anion and its coordination chemistry with coinage metals
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc00318j
Abstract: A tetra(o-tolyl) (μ-hydrido)diborane(4) anion 1, an analogue of [B2H5]− species, was facilely prepared through the reaction of tetra(o-tolyl)diborane(4) with sodium hydride. Unlike common sp2–sp3 diborane species, 1 exhibited a σ-B–B bond nucleophilicity towards NHC-coordinated transition-metal… read more here.
Keywords: hydrido diborane; diborane anion; chemistry; coinage ... See more keywords