Articles with "hydro chloroborylation" as a keyword



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Twisted push-pull disilenes obtained by direct 1,2-hydro/chloroborylation of a silylone.

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Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc02160a

Abstract: Overcrowded 1-amino-2-boryldisilenes were isolated as blue crystals by the direct hydro/chloroborylation of a cyclic (alkyl)(amino)silylene-coordinated monatomic silicon complex (silylone) with 9-BBN (BBN = borabicyclo[3.3.1]nonane) hydride/chloride. The extreme twisting and push-pull effect around the SiSi bonds… read more here.

Keywords: direct hydro; silylone; push pull; hydro chloroborylation ... See more keywords