Palladium Hydride-Enabled Hydroalkenylation of Strained Molecules.
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DOI: 10.1021/jacs.2c09045
Abstract: We report the first palladium hydride enabled hydroalkenylation of strained molecules. This new mild protocol proceeds via a regio- and chemoselective hydropalladation step, followed by a photoinduced radical alkyl Heck reaction. This methodology represents a… read more here.
Keywords: hydroalkenylation; hydride enabled; palladium hydride; hydroalkenylation strained ... See more keywords
Enhanced Excited-State Hydricity of Pd-H Allows for Unusual Head-to-Tail Hydroalkenylation of Alkenes.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c02410
Abstract: Photoinduced enhancement of hydricity of palladium hydride species enables unprecedented hydride addition-like ("hydridic") hydropalladation of electron-deficient alkenes, which allows for chemoselective head-to-tail cross-hydroalkenylation of electron-deficient and electron-rich alkenes. This mild and general protocol works with… read more here.
Keywords: head tail; hydroalkenylation; hydricity; enhanced excited ... See more keywords