Iridium-Catalyzed Branch-Selective and Enantioselective Hydroalkenylation of α-Olefins through C-H Cleavage of Enamides.
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DOI: 10.1021/jacs.2c07477
Abstract: Catalytic branch-selective hydrofunctionalization of feedstock α-olefins to form enantioenriched chiral compounds is a particularly attractive yet challenging transformation in asymmetric catalysis. Herein we report an iridium-catalyzed asymmetric hydroalkenylation of α-olefins through directed C-H cleavage of… read more here.
Keywords: hydroalkenylation olefins; selective enantioselective; iridium catalyzed; branch selective ... See more keywords