Decatungstate‐Photocatalyzed Diastereoselective Dearomative Hydroalkylation of Indoles
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202400248
Abstract: In this study, we present an efficient and straightforward dearomative hydroalkylation of indoles. By utilizing alkanes or ethers as alkyl radical sources and employing TBADT as a cost‐effective photocatalyst for direct hydrogen atom transfer (HAT),… read more here.
Keywords: photocatalyzed diastereoselective; dearomative hydroalkylation; hydroalkylation indoles; diastereoselective dearomative ... See more keywords
NiH-catalyzed dearomative hydroalkylation of indoles.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01650h
Abstract: A NiH-catalyzed intermolecular dearomative hydroalkylation of indoles has been developed, which assembles an array of structurally diverse C2-alkylated indolines with moderate to excellent yields. This protocol exhibits good functional group tolerance, allowing for late-stage functionalization… read more here.
Keywords: hydroalkylation indoles; catalyzed dearomative; nih catalyzed; dearomative hydroalkylation ... See more keywords