Coordination Assistance: A Powerful Strategy for Metal-Catalyzed Regio- and Enantioselective Hydroalkynylation of Internal Alkenes.
Sign Up to like & getrecommendations! Published in 2023 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00713
Abstract: ConspectusAlkenes are versatile compounds that are readily available on a large scale from industry or through organic synthesis. The widespread occurrence of alkenes provides the continuous impetus for the development of catalytic asymmetric alkene hydrofunctionalizations,… read more here.
Keywords: regio; hydroalkynylation; coordination assistance; internal alkenes ... See more keywords
Simple ZnEt2 as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt02700a
Abstract: Expanding the possibilities of the use of simple and available ZnEt2 as a catalyst, the hydroalkynylation of carbodiimides with a variety of alkynes to obtain unsaturated substituted amidines is described in this work. Different stoichiometric… read more here.
Keywords: simple znet2; catalyst carbodiimide; znet2 catalyst; hydroalkynylation ... See more keywords