Computational mechanistic study on Pd-catalyzed stereoselective synthesis of Z-1,3- and E-1,4-enynes from ligand-controlled regiodivergent hydroalkynylations of allenamides
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DOI: 10.1016/j.mcat.2020.110765
Abstract: Abstract Density functional theory (DFT) calculations show that regardless of using BrettPhos or (o-OMePh)3P ligand, the Pd-catalyzed synthesis of both 1,3- and 1,4-enynes from hydroalkynylations of allenamides proceeds through the hydropalladation mechanism, rather than the… read more here.
Keywords: computational mechanistic; mechanistic study; synthesis enynes; hydroalkynylations allenamides ... See more keywords