Reversible 1,1-hydroaluminations and C-H activation in reactions of a cyclic (alkyl)(amino) carbene with alane.
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DOI: 10.1039/c8cc05013a
Abstract: Varying the reaction ratio of cyclic (alkyl)(amino) carbene (cAACEt) with AlH3·NEtMe2 leads to the isolation of (cAACEtH)AlH2·NEtMe21 and (cAACEtH)2Al(μ-H)2AlH2·NEtMe22 and the first example of a monomeric dialkyl-aluminum hydride (cAACEtH)2AlH 3. VT and 1H-1H EXSY NMR… read more here.
Keywords: amino carbene; alkyl amino; reversible hydroaluminations; hydroaluminations activation ... See more keywords