Rhodium-/Iridium-Catalyzed Hydroamination for the Synthesis of 1,2-, 1,3-, or 1,4-Diamines.
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DOI: 10.1021/acscatal.2c01835
Abstract: An Ir-catalyzed regioselective hydroamination of allyl amines using aryl amines and catalyst-controlled regiodivergent hydroamination of allylic and homoallylic amines with aniline nucleophiles are reported. The directed hydroamination reactions afford a variety of 1,2-, 1,3-, and… read more here.
Keywords: hydroamination synthesis; hydroamination; iridium catalyzed; synthesis diamines ... See more keywords