Mechanistic Studies of Nickel-Catalyzed Hydroarylation of Styrenes.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c03395
Abstract: The mechanism of nickel-catalyzed hydroarylation of styrenes has been explored with density functional theory. Instead of the stepwise pathway via a Ni(II)-H species, computational results unveil that the concerted RO-H oxidative addition/olefin insertion takes place… read more here.
Keywords: catalyzed hydroarylation; mechanistic studies; studies nickel; hydroarylation styrenes ... See more keywords
Nickel-Catalyzed Regiodivergent Reductive Hydroarylation of Styrenes
Sign Up to like & getrecommendations! Published in 2021 at "Synlett"
DOI: 10.1055/a-1523-3228
Abstract: We report a ligand-controlled nickel-catalyzed reductive hydroarylation of styrenes with predictable and controllable regioselectivity. With a diamine ligand, the reaction produces selective linear hydroarylation products. Alternatively, with a chiral PyrOx ligand, branch-selective enantioenriched 1,1-diarylalkane products… read more here.
Keywords: nickel catalyzed; hydroarylation styrenes; catalyzed regiodivergent; reductive hydroarylation ... See more keywords