N-Heterocyclic Carbene Ligand-Controlled Regioselectivity for Nickel-Catalyzed Hydroarylation of Vinylarenes with Benzothiazoles.
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DOI: 10.1021/acs.orglett.9b01645
Abstract: A facile regioselective switch for nickel-catalyzed hydroarylation of vinylarenes with benzothiazoles has been developed, which relies on the simple structural variation of novel Ni(II) complexes of the type Ni(NHC)[P(OR)3]Br2. Using magnesium turnings as the reductant,… read more here.
Keywords: catalyzed hydroarylation; nickel catalyzed; hydroarylation vinylarenes; vinylarenes benzothiazoles ... See more keywords