Radical-initiated alkene hydroauration as a route to gold(III) alkyls: an experimental and computational study
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DOI: 10.1039/c7ra13481a
Abstract: The hydroauration of functionalised 1-alkenes by the gold(III) hydride (C^NOMe^C)AuH is initiated by organic radicals and proceeds via (C^N^C)Au(II) radical intermediates following a bimolecular outer-sphere mechanism. The outcome of these reactions is determined by the… read more here.
Keywords: gold iii; initiated alkene; hydroauration; radical initiated ... See more keywords