Reductive hydrobenzylation of terminal alkynes via photoredox and nickel dual catalysis.
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DOI: 10.1039/d1cc03668h
Abstract: A photoredox/nickel dual catalyzed reductive hydrobenzylation of alkynes and benzyl chlorides by employing alkyl amines as a stoichiometric reductant is described. This synergistic protocol proceeds via Markovnikov-selective migratory insertion of an alkyne into nickel hydride,… read more here.
Keywords: photoredox nickel; hydrobenzylation terminal; reductive hydrobenzylation; nickel dual ... See more keywords