Regioselective Multiboration and Hydroboration of Alkenes and Alkynes Enabled by a Platinum Single-Atom Catalyst
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DOI: 10.1021/acscatal.5c03767
Abstract: Selective multiboration including di- and triboration and hydroboration of alkynes and alkenes face significant challenges in organic synthesis, including achieving high regioselectivity, functional group tolerance, and catalyst stability while requiring mild conditions to maintain reactivity.… read more here.
Keywords: hydroboration alkenes; catalyst; hydroboration; single atom ... See more keywords
Heterogeneous Additive-Free Hydroboration of Alkenes Using Cu–Ni/Al2O3: Concerted Catalysis Assisted by Acid–Base Properties and Alloying Effects
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DOI: 10.1021/acscatal.8b04988
Abstract: This study describes our development of a Cu-based heterogeneous catalytic system for additive-free hydroboration of alkenes. Surveying monometallic Cu supported on various oxides revealed that Al2... read more here.
Keywords: free hydroboration; additive free; hydroboration alkenes; catalysis ... See more keywords
Aluminium complex-catalysed hydroboration of alkenes and alkynes
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DOI: 10.1039/c9nj01859j
Abstract: Catalytic hydroboration of terminal alkenes/alkynes with HBpin using the Al(III) catalyst, [κ2-{Ph2P(=Se)NCH2(C5H4N)}Al(CH3)2] (1), under mild and solvent-free conditions to afford corresponding alkyl/alkenyl boronate esters in high yield is reported. read more here.
Keywords: hydroboration alkenes; aluminium complex; alkenes alkynes; catalysed hydroboration ... See more keywords