Cu-Catalyzed Hydroboration of Benzylidenecyclopropanes: Reaction Optimization, (Hetero)Aryl Scope, and Origins of Pathway Selectivity.
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DOI: 10.1021/acscatal.9b03557
Abstract: The copper-catalyzed hydroboration of benzylidenecyclopropanes, conveniently accessed in one step from readily available benzaldehydes, is reported. Under otherwise identical reaction conditions, two distinct phosphine ligands grant access to different products by either suppressing or promoting… read more here.
Keywords: reaction optimization; catalyzed hydroboration; hydroboration benzylidenecyclopropanes; benzylidenecyclopropanes reaction ... See more keywords