Mechanism of Hydroboration of CO2 Using an Fe Catalyst: What Controls the Reactivity and Product Selectivity?
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02812
Abstract: Using a combination of density functional theory (DFT) and ab initio complete active space self-consistent field (CASSCF) calculations, various elementary steps in the mechanism of the reductive hydroboration of CO2 to two-electron-reduced boryl formate, four-electron-reduced… read more here.
Keywords: catalyst; product selectivity; hydroboration co2; mechanism ... See more keywords
Selective Ni-Catalyzed Hydroboration of CO2 to the Formaldehyde Level Enabled by New PSiP Ligation
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00497
Abstract: The synthesis and characterization of group 10 metal pincer complexes supported by a new bis(indolylphosphino)silyl ligand are described, including the synthesis of Ni, Pd, and Pt hydride species. Solution NMR and single-crystal X-ray data revealed… read more here.
Keywords: formaldehyde level; co2 formaldehyde; co2; hydroboration co2 ... See more keywords