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Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c01866
Abstract: Commercially available and inexpensive lithium tert-butoxide (tBuOLi) acts as a good precatalyst for the hydroboration of esters, lactones, and epoxides using pinacolborane as a borylation agent. Functional groups such as cyano-, nitro-, amino-, vinyl, and…
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Keywords:
promoted hydroboration;
hydroboration esters;
hydroboration;
esters epoxides ... See more keywords
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Published in 2024 at "Dalton transactions"
DOI: 10.1039/d3dt04084d
Abstract: The conjugated bis-guanidinate (CBG)-supported zinc hydride {LZnH}2; L = {(ArHN)(ArN)-CN-C(NAr)(NHAr); Ar = 2,6-Et2-C6H3} (I) is utilized as a catalyst for the hydroboration of esters with pinacolborane (HBpin) under mild reaction conditions. Various aryl and alkyl…
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Keywords:
zinc hydride;
hydride catalyzed;
hydroboration;
hydroboration esters ... See more keywords