Mechanism and Regioselectivity of the Iron-Catalyzed Hydroboration of N-Heteroarenes: A Computational Study
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DOI: 10.1021/acs.organomet.9b00292
Abstract: Iron complex Cp*(Ph2PC6H4S)Fe was recently reported to regioselectively catalyze the hydroboration of N-heteroarenes with pinacolborane (HBpin). Density functional calculations were performed to el... read more here.
Keywords: iron catalyzed; hydroboration heteroarenes; regioselectivity iron; mechanism regioselectivity ... See more keywords
Nickel-Catalyzed Regioselective 1,4-Hydroboration of N-Heteroarenes
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DOI: 10.1021/acscatal.8b01166
Abstract: Combinations of Ni(acac)2 with phosphine ligands were found to catalyze the regioselective hydroboration of N-heteroarenes with pinacolborane, affording N-borylated 1,4-reduction products. Preliminary mechanistic studies have focused on the isolation and study of potential intermediates in… read more here.
Keywords: regioselective hydroboration; catalyzed regioselective; hydroboration heteroarenes; nickel catalyzed ... See more keywords
Iron-Catalyzed 1,2-Selective Hydroboration of N-Heteroarenes.
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DOI: 10.1021/jacs.7b11416
Abstract: A N2-bridged diiron complex [Cp*(Ph2PC6H4S)Fe]2(μ-N2) (1) has been found to catalyze the hydroboration of N-heteroarenes with pinacolborane, giving N-borylated 1,2-reduced products with high regioselectivity. The catalysis is initiated by coordination of N-heteroarenes to the iron… read more here.
Keywords: selective hydroboration; catalyzed selective; hydroboration heteroarenes; heteroarenes iron ... See more keywords