Iron‐Salen Complexes for Hydroboration of Ketones: Enhancing Reactivity via Ligand Modulation at the Phenylene Bridge
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DOI: 10.1002/cctc.202401986
Abstract: Two iron salen complexes, Fe─di─F and Fe─di─Me, have been synthesized by incorporating substituents that possess distinct electronic properties to the phenyl diimine bridge of salen ligands, aiming to enhance the catalytic efficiency. These structural modifications… read more here.
Keywords: salen complexes; hydroboration ketones; iron salen;
Iron(ii) coordination polymer catalysed hydroboration of ketones.
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DOI: 10.1039/c8dt02134a
Abstract: Catalytic hydroboration of ketones with pinacolborane was achieved with a 2D iron(ii) coordination polymer (CP) of a divergent 4,2';6',4''-terpyridine (tpy) derivative under mild conditions with high efficiency. This solid iron catalyst system is more active… read more here.
Keywords: iron coordination; hydroboration ketones; coordination polymer; hydroboration ... See more keywords
Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
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DOI: 10.1039/d2ra03731a
Abstract: A new diplumbane, namely [Pb(CH2SiMe3)3]2, was synthesized and structurally characterized. This group 14 element compound was found to catalyse the hydroboration of ketones and aldehydes under mild conditions without the use of additives and solvents,… read more here.
Keywords: ketones aldehydes; diplumbane catalysed; solvent additive; hydroboration ketones ... See more keywords