Nickel-Catalyzed Enantioselective Hydroboration of Vinylarenes.
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DOI: 10.1021/acs.orglett.1c04073
Abstract: The enantioselective hydroboration of vinylarenes catalyzed by a chiral, nonracemic nickel catalyst is presented as a facile method for generating chiral benzylic boronate esters. Various vinylarenes react with bis(pinacolato)diboron (B2pin2) in the presence of MeOH… read more here.
Keywords: hydroboration vinylarenes; nickel catalyzed; enantioselective hydroboration; catalyzed enantioselective ... See more keywords