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Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc00663k
Abstract: The highly enantioselective copper-catalyzed propargylic amination of propargylic esters with amine hydrochloride salts has been realized for the first time using copper salts with chiral N,N,P-ligands. This method features a broad substrate scope and wide…
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Keywords:
copper;
amine hydrochloride;
catalyzed propargylic;
hydrochloride salts ... See more keywords
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Published in 2020 at "Synlett"
DOI: 10.1055/s-0040-1706413
Abstract: While imines are frequently used substrates in asymmetric Bronsted acid catalysis, their corresponding salts are generally considered unsuitable reaction partners. Such processes are challenging because they require the successful competition of a catalytic amount of…
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Keywords:
acids catalyze;
chiral nsted;
imine hydrochloride;
nsted acids ... See more keywords
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Published in 2021 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229621008950
Abstract: The crystal structures of the hydrochloride salts of nine substituted tryptamines, namely, 1-methyltryptammonium chloride, C11H15N2+·Cl-, (1), 2-methyl-1-phenyltryptammonium chloride, C17H19N2+·Cl-, (2), 5-methoxytryptammonium chloride, C11H15N2O+·Cl-, (3), 5-bromotryptammonium chloride, C10H12BrN2+·Cl-, (4), 5-chlorotryptammonium chloride, C10H12ClN2+·Cl-, (5), 5-fluorotryptammonium chloride, C10H12FN2+·Cl-,…
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Keywords:
substituted tryptamines;
methyltryptammonium chloride;
hydrochloride salts;
crystalline forms ... See more keywords