A Convenient and Stable Heterogeneous Nickel Catalyst for Hydrodehalogenation of Aryl Halides Using Molecular Hydrogen
Sign Up to like & getrecommendations! Published in 2022 at "Chemsuschem"
DOI: 10.1002/cssc.202102315
Abstract: Abstract Hydrodehalogenation is an effective strategy for transforming persistent and potentially toxic organohalides into their more benign congeners. Common methods utilize Pd/C or Raney‐nickel as catalysts, which are either expensive or have safety concerns. In… read more here.
Keywords: hydrodehalogenation; catalyst; convenient stable; heterogeneous nickel ... See more keywords
Catalytic hydrodehalogenation over supported gold: Electron transfer versus hydride transfer
Sign Up to like & getrecommendations! Published in 2018 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2018.03.032
Abstract: Abstract Selective hydrodehalogenation of a variety of aromatic halides (e.g., halogen subsitute phenones and hexafluorobenzene) using isopropanol as the hydrogen source was successfully achieved over supported Au nanoparticles. Distinct reaction pathways were established based on… read more here.
Keywords: hydrodehalogenation; catalytic hydrodehalogenation; electron transfer; transfer ... See more keywords
Rapid hydrodehalogenation of chlorinated benzoic acids using mechano-thermally prepared Raney alloy with enhanced kinetics
Sign Up to like & getrecommendations! Published in 2021 at "Journal of environmental chemical engineering"
DOI: 10.1016/j.jece.2021.105764
Abstract: Abstract The present study reports on the degradation of chlorinated benzoic acids (CBAs), commonly present in the environment as pollutants, by a hydrodehalogenation reaction utilizing the Raney Al-Ni alloy (50:50 wt% Al:Ni). The hydrodehalogenation reaction using… read more here.
Keywords: chlorinated benzoic; benzoic acids; hydrodehalogenation; alloy enhanced ... See more keywords