Palladium-Catalyzed Electrooxidative Hydrofluorination of Aryl-Substituted Alkenes with a Nucleophilic Fluorine Source.
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DOI: 10.1021/acs.orglett.2c04045
Abstract: Herein, we report an electrocatalytic hydrofluorination of aryl-substituted alkenes with a nucleophilic fluorine source. The merger of palladium catalysis with electrooxidation enables the transformation of various substrates ranging from styrenes to more challenging α,β-unsaturated carbonyl… read more here.
Keywords: alkenes nucleophilic; nucleophilic fluorine; hydrofluorination; hydrofluorination aryl ... See more keywords
Nickel-Catalyzed Hydrofluorination of Unactivated Alkenes through a HAT Pathway
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DOI: 10.1021/acscatal.0c03884
Abstract: We report the hydrofluorination of unactivated alkenes using N-fluorobenzenesulfonimide as a fluorination reagent. The reaction produces exclusively Markovnikov hydrofluorination products under mil... read more here.
Keywords: alkenes hat; catalyzed hydrofluorination; hydrofluorination unactivated; hydrofluorination ... See more keywords