Ligand-Controlled Regiodivergent Hydroformylation of Ynamides: A Stereospecific and Regioselective Access to 2- and 3-Aminoacroleins.
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DOI: 10.1021/acs.orglett.9b03566
Abstract: The rhodium-catalyzed hydroformylation of ynamides is described and gives selective access to 2- or 3-aminoacrolein derivatives. The regioselectivity of this carbonylation can be completely controlled at will thanks to the nature of the ligand used.… read more here.
Keywords: hydroformylation ynamides; hydroformylation; controlled regiodivergent; ligand controlled ... See more keywords