Articles with "hydrogen carbonate" as a keyword



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Decomposition of Potassium Hydrogen Carbonate: Thermochemistry, Kinetics, and Textural Changes in Solids

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Published in 2019 at "Industrial & Engineering Chemistry Research"

DOI: 10.1021/acs.iecr.8b06151

Abstract: To determine unbiased rates of the decomposition of KHCO3, slowly increasing- and constant-temperature TGA methods were employed with small, finely ground samples. Such reaction provides a novel, p... read more here.

Keywords: thermochemistry kinetics; decomposition potassium; hydrogen carbonate; kinetics textural ... See more keywords
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Eu(iii) and Tb(iii) complexes of 6-fold coordinating ligands showing high affinity for the hydrogen carbonate ion: a spectroscopic and thermodynamic study.

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Published in 2019 at "Dalton transactions"

DOI: 10.1039/c8dt03621g

Abstract: In the present contribution, four classes of Ln(iii) complexes (Ln = Eu and Tb) have been synthesized and characterized in aqueous solution. They differ by charge, Ln(bpcd)+ [bpcd2- = N,N'-bis(2-pyridylmethyl)-trans-1,2-diaminocyclohexane N,N'-diacetate] and Ln(bQcd)+ (bQcd2- =… read more here.

Keywords: iii; iii complexes; ion; hydrogen carbonate ... See more keywords