Stabilizing hydrogen-mediated sextuple bonds by quintuple superatomic bonding and a bond.
Sign Up to like & getrecommendations! Published in 2023 at "Nanoscale"
DOI: 10.1039/d3nr00188a
Abstract: Multiple bond orders of four and five are frequently obtained for d-block elements. However, compounds with sextuple bonding (2σ, 2π, and 2δ), for instance, Cr2, Mo2 and W2, are less stable and trapped only in… read more here.
Keywords: quintuple superatomic; hydrogen mediated; superatomic bonding; mediated sextuple ... See more keywords
Hydrogen-mediated acid-base transformation of Ni supported Mo5N6 for hydrogenative rearrangement of furfural derivatives
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Materials Chemistry A"
DOI: 10.1039/d4ta02076f
Abstract: The hydrogenative rearrangement of bioderived furfural derivatives to various cyclopentanone derivatives is vital for synthesizing fine chemicals but challenging owing to the complex cascade reaction network. Herein, a noble metal–free... read more here.
Keywords: mediated acid; hydrogen mediated; hydrogenative rearrangement; furfural derivatives ... See more keywords
Hydrogen-Mediated Noncovalent Interactions in Solids: What Can NMR Crystallography Tell About?
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25163757
Abstract: Hydrogen atoms play a crucial role in the aggregation of organic (bio)molecules through diverse number of noncovalent interactions that they mediate, such as electrostatic in proton transfer systems, hydrogen bonding, and CH–π interactions, to mention… read more here.
Keywords: hydrogen mediated; nmr crystallography; mediated noncovalent; noncovalent interactions ... See more keywords