Articles with "hydrogen migration" as a keyword



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The hydrogen migration in cryogenic tubes of superconductive accelerator with gas source

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Published in 2018 at "Radiation Detection Technology and Methods"

DOI: 10.1007/s41605-018-0086-7

Abstract: BackgroundIn superconductive linear accelerator, the performance and stability can be impacted by gas adsorbed on cryogenic surfaces adversely. The cryogenic devices usually work at 4.2 K or 1.9 K and are refrigerated by normal or super fluid… read more here.

Keywords: cryogenic tubes; hydrogen migration; gas; migration ... See more keywords
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Stopping Hydrogen Migration in Its Tracks: The First Successful Synthesis of Group Ten Scorpionate Complexes Based on Azaindole Scaffolds.

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Published in 2019 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.8b02456

Abstract: The first successful synthesis and characterization of group 10 complexes featuring flexible scorpionate ligands based on 7-azaindole heterocycles are reported herein. Addition of 2 equiv of either K[HB(azaindolyl)3] or Li[HB(Me)(azaindolyl)2] to [M(μ-Cl)(η,1η2-COEOMe)]2 leads to the… read more here.

Keywords: group; hydrogen migration; successful synthesis; based azaindole ... See more keywords
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Rhenium-Catalyzed Cyclization via 1,2-Iodine and 1,5-Hydrogen Migration for the Synthesis of 2-Iodo-1H-indenes.

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Published in 2019 at "Organic letters"

DOI: 10.1021/acs.orglett.9b02380

Abstract: A rhenium complex catalyzed the formation of 2-iodo-1H-indene derivatives through iodine and hydrogen migration of 3-iodopropargyl ethers. The reaction proceeded via generation of 1-iodoalkenylrhenium carbene species by sequential 1,2-iodine and 1,5-hydrogen shifts with readily available… read more here.

Keywords: hydrogen; hydrogen migration; rhenium catalyzed; iodo ... See more keywords