Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature
Sign Up to like & getrecommendations! Published in 2020 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202000241
Abstract: A cyclometalated rhodium complex has been found to show excellent activity in dehydrogenation of methanol at room temperature. This feature allows for the catalytic transfer hydrogenation of various aldehydes with methanol as both hydrogen source… read more here.
Keywords: temperature; hydrogen; methanol; room temperature ... See more keywords
Heterogeneous AgPd Alloy Nanocatalyst for Selective Reduction of Aromatic Nitro Compounds Using Formic Acid as Hydrogen Source
Sign Up to like & getrecommendations! Published in 2020 at "Catalysis Letters"
DOI: 10.1007/s10562-020-03098-y
Abstract: Abstract A Heterogeneous catalyst developed for selective reduction of nitroarenes to the analogous anilines using formic acid as hydrogen source. This catalytic procedure offers a simplistic path to prepare aromatic amines in good to excellent… read more here.
Keywords: selective reduction; using formic; formic acid; hydrogen source ... See more keywords
Exploration of Cu-catalyzed regioselective hydrodehalogenation of o-haloanilides using EtOH as hydrogen source
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.121844
Abstract: Abstract In present work, we have explored a Cu(acac)2/vasicine-catalyzed regioselective hydrodehalogenation methodology of o-haloanilides using EtOH as hydrogen source and solvent. The catalytic system could selectively dehalogenate 2-Br and 2-I, and features regioselective, efficient and… read more here.
Keywords: catalyzed regioselective; regioselective hydrodehalogenation; etoh hydrogen; using etoh ... See more keywords
Depolymerization of Lignin over a Ni–Pd Bimetallic Catalyst Using Isopropanol as an in Situ Hydrogen Source
Sign Up to like & getrecommendations! Published in 2019 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.9b01976
Abstract: Performance of Ni–Pd bimetallic catalysts on depolymerization of lignin into monomeric phenols was investigated using isoproponal as an in situ hydrogen source. The performance of catalysts and the effects of temperature and starting lignins were… read more here.
Keywords: microscopy; depolymerization; situ hydrogen; depolymerization lignin ... See more keywords
An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc03431a
Abstract: Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation… read more here.
Keywords: h2o hydrogen; catalyst; hydrogen source; hydroaminomethylation olefins ... See more keywords
Nickel−palladium alloy nanoparticles supported on reduced graphene oxide decorated with metallic aluminum nanoparticles (Al-rGO/NiPd): a multifunctional catalyst for the transfer hydrogenation of nitroarenes and olefins using water as a hydrogen source
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry frontiers"
DOI: 10.1039/d0qi01363c
Abstract: We report herein an innovative design and synthesis of a novel multifunctional nanocatalyst for the transfer hydrogenation (TH) of nitroarenes and olefins using water as a hydrogen source and solvent. The presented nanocatalyst is composed… read more here.
Keywords: hydrogen; transfer hydrogenation; hydrogen source; transfer ... See more keywords