Alkali ions secure hydrides for catalytic hydrogenation
Sign Up to like & getrecommendations! Published in 2020 at "Nature Catalysis"
DOI: 10.1038/s41929-020-0481-6
Abstract: Catalytic hydrogenation is one of the backbones of the chemical industry. Controlling the reaction behaviour of the activated hydrogen species over oxide-supported metal catalysts is essential. Aside from the expected addition to substrates, the activated… read more here.
Keywords: alkali ions; atomically dispersed; hydrogenation; hydrogen species ... See more keywords
Polar hydrogen species mediated nitroarenes selective reduction to anilines over an [FeMo]Sx catalyst.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt03107d
Abstract: We herein present an efficient approach for the chemoselective synthesis of arylamines from nitroarenes and hydrazine over an iron-molybdenum sulfide catalyst ([FeMo]Sx). The heterogeneous hydrogen transfer reduction can be efficiently carried out at 30 °C… read more here.
Keywords: catalyst; species mediated; hydrogen species; polar hydrogen ... See more keywords
Confinement Effect and Hydrogen Species Modulation toward Enhanced Electrochemical CO2 Reduction to Ethanol
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DOI: 10.34133/research.0796
Abstract: The protonation process of adsorbed *CO intermediates has been widely recognized as a critical determinant governing product selectivity in electrocatalytic carbon dioxide reduction reaction (eCO2RR). However, the active hydrogen species and mechanism of *CO protonation… read more here.
Keywords: acid eco2rr; confinement effect; eco2rr; hydrogen species ... See more keywords