Coupling Glucose Dehydrogenation with CO2 Hydrogenation by Hydrogen Transfer in Aqueous Media at Room Temperature.
Sign Up to like & getrecommendations! Published in 2018 at "ChemSusChem"
DOI: 10.1002/cssc.201800570
Abstract: Conversion of CO2 into value-added chemicals and fuels provides a direct solution to reduce excessive CO2 in the atmosphere. Herein, a novel catalytic reaction system is presented by coupling the dehydrogenation of glucose with the… read more here.
Keywords: hydrogenation; dehydrogenation co2; co2; glucose dehydrogenation ... See more keywords
Hydrogen transfer and quinone/hydroquinone transitions in graphene-based materials
Sign Up to like & getrecommendations! Published in 2018 at "Carbon"
DOI: 10.1016/j.carbon.2017.10.024
Abstract: Abstract A computational quantum chemistry study, guided by critical experimental facts and issues, is carried out in an effort to provide a long-missing link between the very much intertwined processes of hydrogen, oxygen and electron… read more here.
Keywords: graphene based; kcal mol; quinone hydroquinone; hydrogen transfer ... See more keywords
Thermal treatment of FCC slurry oil under hydrogen: Correlation of hydrogen transfer ability with carbonization performance of the fractions
Sign Up to like & getrecommendations! Published in 2018 at "Fuel"
DOI: 10.1016/j.fuel.2018.06.073
Abstract: Abstract Hydrogen transfer property is of great importance in the carbonization of heavy oils. Thermal treatment under hydrogen was performed on a raw slurry oil (SO) from FCC process. The theoretical hydrogen-donating property of SO… read more here.
Keywords: carbonization; hydrogen; treatment; hydrogen transfer ... See more keywords
Hydrogen transfer route and interaction mechanism during co-pyrolysis of Xilinhot lignite and rice husk
Sign Up to like & getrecommendations! Published in 2019 at "Fuel Processing Technology"
DOI: 10.1016/j.fuproc.2019.04.022
Abstract: Abstract In this study, co-pyrolysis of Xilinhot lignite (XL) and rice husk (RH) was carried out in an aluminum retort to investigate potential interaction mechanism by analyzing the product distribution and hydrogen transfer route. Results… read more here.
Keywords: transfer route; hydrogen transfer; hydrogen; pyrolysis ... See more keywords
Hydrogen Transfer-Mediated Multicomponent Reaction for Direct Synthesis of Quinazolines by a Naphthyridine-Based Iridium Catalyst
Sign Up to like & getrecommendations! Published in 2020 at "iScience"
DOI: 10.1016/j.isci.2020.101003
Abstract: Summary Selective linkage of renewable alcohols and ammonia into functional products would not only eliminate the prepreparation steps to generate active amino agents but also help in the conservation of our finite fossil carbon resources… read more here.
Keywords: hydrogen; based iridium; hydrogen transfer; naphthyridine based ... See more keywords
Substitutions of Amino Acid Residues in the Substrate Binding Site of Horse Liver Alcohol Dehydrogenase Have Small Effects on the Structures but Significantly Affect Catalysis of Hydrogen Transfer.
Sign Up to like & getrecommendations! Published in 2020 at "Biochemistry"
DOI: 10.1021/acs.biochem.9b01074
Abstract: Previous studies showed that the L57F and F93W alcohol dehydrogenases catalyze the oxidation of benzyl alcohol with some quantum mechanical hydrogen tunneling, whereas the V203A enzyme has diminished tunneling. Here, steady-state kinetics for the L57F… read more here.
Keywords: hydrogen transfer; alcohol; rate constants; hydrogen ... See more keywords
Isotope Labeling to Study the Hydrogen Transfer Route during Lignite Modification in a Subcritical D2O–CO System
Sign Up to like & getrecommendations! Published in 2020 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.9b04472
Abstract: The hydrogen transfer reaction is one of the key chemical processes of coal conversion. The elucidation of the hydrogen transfer mechanism is essential for rational control of the properties and di... read more here.
Keywords: isotope labeling; hydrogen; transfer route; labeling study ... See more keywords
Efficient and Adaptive Methods for Computing Accurate Potential Surfaces for Quantum Nuclear Effects: Applications to Hydrogen-Transfer Reactions.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of chemical theory and computation"
DOI: 10.1021/acs.jctc.7b00927
Abstract: We present two sampling measures to gauge critical regions of potential energy surfaces. These sampling measures employ (a) the instantaneous quantum wavepacket density, an approximation to the (b) potential surface, its (c) gradients, and (d)… read more here.
Keywords: transfer reactions; hydrogen transfer; potential surfaces; quantum nuclear ... See more keywords
Reversibility of the Hydrogen Transfer in TKX-50 and Its Influence on Impact Sensitivity: An Exceptional Case from Common Energetic Materials
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b07663
Abstract: Hydrogen transfer (HT) has been confirmed to possibly serve as a crucial step to initiate and control the decay of common energetic materials (EMs). Nevertheless, the case of currently thriving energetic ionic salts (EISs), as… read more here.
Keywords: energetic materials; common energetic; case; transfer ... See more keywords
Hydrogen Transfer Activation via Stabilization of Coordinatively Vacant Sites: Tuning Long-Range π-System Electronic Interaction between Ru(0) and NHC Pendants
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00850
Abstract: The insertion of a pyridine substituent on the lateral chain of N-heterocyclic carbene ligands enhances the catalytic activity of [Ru(CO)2(cyclopentadienone)(NHC)] complexes, precursors of Shvo-type catalysts, toward the hydrogenation of 4-fluoroacetophenone in refluxing 2-propanol as hydrogen… read more here.
Keywords: hydrogen transfer; via stabilization; transfer activation; nhc ... See more keywords
Exploring Tandem Ruthenium-Catalyzed Hydrogen Transfer and SNAr Chemistry.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b03441
Abstract: A hydrogen-transfer strategy for the catalytic functionalization of benzylic alcohols via electronic arene activation, accessing a diverse range of bespoke diaryl ethers and aryl amines in excellent isolated yields (38 examples, 70% average yield), is… read more here.
Keywords: tandem ruthenium; hydrogen transfer; exploring tandem; chemistry ... See more keywords