Controlling O2 Reactivity in Synthetic Analogues of [NiFeS]- and [NiFeSe]-Hydrogenase Active Sites.
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DOI: 10.1021/jacs.9b07448
Abstract: Strategies for limiting, or reversing, the degradation of air-sensitive, base metal catalysts for the hydrogen evolution/oxidation reaction on contact with adventitious O2 are guided by Nature's design of hydrogenase active sites. The affinity of oxygen… read more here.
Keywords: active sites; hydrogenase active; reactivity; oxygen uptake ... See more keywords