The Power of the Secondary Sphere: Modulating Hydrogenase Activity in Nickel-Substituted Rubredoxin
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DOI: 10.2210/pdb6nw1/pdb
Abstract: Secondary sphere interactions are known to significantly impact catalytic rates within biological systems as well as synthetic molecular catalysts. The [NiFe] hydrogenase enzymes oxidize and produc... read more here.
Keywords: hydrogenase activity; secondary sphere; power secondary; hydrogenase ... See more keywords
Theoretical Insights into the Aerobic Hydrogenase Activity of Molybdenum–Copper CO Dehydrogenase
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DOI: 10.3390/inorganics7110135
Abstract: The Mo/Cu-dependent CO dehydrogenase from O. carboxydovorans is an enzyme that is able to catalyse CO oxidation to CO 2 ; moreover, it also expresses hydrogenase activity, as it is able to oxidize H 2… read more here.
Keywords: dehydrogenase; copper; hydrogenase; hydrogenase activity ... See more keywords