High‐Density Rare‐Earth Single‐Atom‐Triggered Unconventional Transition of Adsorption Configuration on La1Pd Monatomic Alloy Metallene for Sustainable Electrocatalytic Alkynol Semi‐Hydrogenation
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DOI: 10.1002/adfm.202404648
Abstract: Electrocatalytic alkynol semi‐hydrogenation for the high‐value chemicals alkenol with mild conditions and carbon‐free emission is a potentially green and sustainable alternative to conventional thermocatalytic routes, which generally involves the design of electrocatalysts with high activity… read more here.
Keywords: mby; hydrogenation; adsorption; single atom ... See more keywords
Modulating the Hydrogenation Mechanism of Electrochemical CO2 Reduction Using Ruthenium Atomic Species on Bismuth
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DOI: 10.1002/adfm.202405835
Abstract: The conversion of CO2 into formate through electrochemical methods is emerging as an elegant approach for industrial‐scale CO2 utilization in the near future. Although Bismuth (Bi)‐based materials have shown promise thank to their excellent selectivity,… read more here.
Keywords: atomic species; ruthenium atomic; hydrogenation; co2 ... See more keywords
Competitive Anchoring of Mo Atoms Induces Pt Atoms Agglomeration and Enhanced Electronic Effects: Elevated Activity and Selectivity for Carbon Disulfide Hydrogenation
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DOI: 10.1002/adfm.202505879
Abstract: High‐electron‐density Pt0 nanoparticles (NPs) with excellent hydrogen activation and spillover capacity offer unique advantages in volatile organic sulfur selective hydrogenation reactions. Taking advantage of the more preferential and effective anchoring of Mo atoms at the… read more here.
Keywords: competitive anchoring; carbon disulfide; hydrogenation; selectivity ... See more keywords
Electronically Modulated Defective Cu 1.81 S by FeN 4 for High‐Performance Nitroarene Hydrogenation
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DOI: 10.1002/adfm.202524811
Abstract: Copper‐based catalysts are attractive for hydrogenation, exemplified by nitro‑group reduction to industrially important aromatic amines, but are limited by intrinsically weak H 2 activation arising from an inert electronic structure. Herein, a dual‐site catalyst is… read more here.
Keywords: hydrogenation; nitroarene hydrogenation; high performance; electronically modulated ... See more keywords
Advances in Catalytic Applications of Zeolite-Supported Metal Catalysts.
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DOI: 10.1002/adma.202104442
Abstract: Zeolites possessing large specific surface areas, ordered micropores, and adjustable acidity/basicity have emerged as ideal supports to immobilize metal species with small sizes and high dispersities. In recent years, the zeolite-supported metal catalysts have been… read more here.
Keywords: supported metal; applications zeolite; hydrogenation; metal catalysts ... See more keywords
A Magnetically Separable Pd Single‐Atom Catalyst for Efficient Selective Hydrogenation of Phenylacetylene
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DOI: 10.1002/adma.202110455
Abstract: Selective hydrogenation of alkynes to alkenes plays a crucial role in the synthesis of fine chemicals. However, how to achieve high selectivity and effective separation of the catalyst and substrate while obtaining high activity is… read more here.
Keywords: hydrogenation phenylacetylene; catalyst; hydrogenation; single atom ... See more keywords
Unlocking the Potential of Oxide‐Based Catalysts for CO2 Photo‐Hydrogenation: Oxygen Vacancies Promoted C─O Bond Cleavage in Key Intermediates
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DOI: 10.1002/adma.202408906
Abstract: Oxygen vacancies are generally recognized to play significant roles in CO2 adsorption and activation during CO2 hydrogenation. However, by revisiting its structural/electronic affinity for a range of oxygen‐containing intermediates in CO2 hydrogenation processes, the additional… read more here.
Keywords: co2 photo; oxygen; hydrogenation; bond cleavage ... See more keywords
Electrocatalytic Hydrogenation Boosted by Surface Hydroxyls‐Modulated Hydrogen Migration over Nonreducible Oxides
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DOI: 10.1002/adma.202500371
Abstract: The migration of atomic hydrogen species over heterogeneous catalysts is deemed essential for hydrogenation reactions, a process closely related to the catalyst's functionalities. While surface hydroxyls‐assisted hydrogen spillover is well documented on reducible oxide supports,… read more here.
Keywords: migration; hydrogen; surface hydroxyls; hydrogenation ... See more keywords
Atomic Hydrogen Mediated Efficient Electrocatalytic Hydrogenation Reactions.
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DOI: 10.1002/adma.202517022
Abstract: Although atomic hydrogen (H*) is a crucial active species during the electrocatalytic hydrogenation process, its excessive production accelerates its self-quenching into hydrogen (H2), which decreases the reduction efficiency of the target reactant and causes cathode… read more here.
Keywords: efficiency; electrocatalytic hydrogenation; hydrogenation; hydrogenation reactions ... See more keywords
Breaking Trade‐Off between Selectivity and Activity of Nickel‐Based Hydrogenation Catalysts by Tuning Both Steric Effect and d‐Band Center
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DOI: 10.1002/advs.201900054
Abstract: Abstract For selective hydrogenation of chemicals the high selectivity is always at the expense of activity and improving both selectivity and activity is challenging. Here, by chelating with p‐fluorothiophenol (SPhF)‐arrays, both steric and electronic effects… read more here.
Keywords: nickel based; hydrogenation; selectivity activity; band center ... See more keywords
State-of-the-Art Advancements in Photocatalytic Hydrogenation: Reaction Mechanism and Recent Progress in Metal-Organic Framework (MOF)-Based Catalysts.
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DOI: 10.1002/advs.202103361
Abstract: Photocatalytic hydrogenation provides an effective alternative way for the synthesis of industrial chemicals to meet the economic and environment expectations. Especially, over the past few years, metal-organic frameworks (MOFs), featured with tunable structure, porosity, and… read more here.
Keywords: hydrogenation; mofs based; metal organic; recent progress ... See more keywords