Selective Iron-Catalyzed Deaminative Hydrogenation of Amides
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DOI: 10.1021/acs.organomet.6b00816
Abstract: The five-coordinate iron(II) hydride complex (iPrPNP)Fe(H)CO (iPrPNP = N[CH2CH2(PiPr2)]2) was found to selectively catalyze deaminative hydrogenation of amides to the corresponding amines and primary alcohols. It is one of the most active amide hydrogenation catalysts… read more here.
Keywords: hydrogenation; hydrogenation amides; iron catalyzed; deaminative hydrogenation ... See more keywords
Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation
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DOI: 10.1021/acscatal.8b02902
Abstract: Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal–ligand cooperation of the manganese… read more here.
Keywords: deoxygenative hydrogenation; hydrogenation amides; metal; ligand cooperation ... See more keywords