Experimental Evidence of syn H-N-Fe-H Configurational Requirement for Iron-Based Bifunctional Hydrogenation Catalysts.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00328
Abstract: Iron hydrides supported by a pincer ligand of the type HN(CH2CH2PR2)2 (RPNHP) are versatile hydrogenation catalysts. Previous efforts have focused on using CO as an additional ligand to stabilize the hydride species. In this work,… read more here.
Keywords: evidence syn; hydrogenation; experimental evidence; iron hydrides ... See more keywords
NO2 Hydrogenation on Rh Catalysts: Bifurcations and Oscillations at the Nanoscale
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b04123
Abstract: In this work, we report complex kinetic phenomena observed during the reduction of NO2 on rhodium model catalysts followed by field emission microscopy (FEM). This technique uses samples prepared as sharp tips, mimicking the size… read more here.
Keywords: oscillations nanoscale; microscopy; catalysts bifurcations; hydrogenation catalysts ... See more keywords