Experimental determination of the hydrogenation/dehydrogenation - Equilibrium of the LOHC system H0/H18-dibenzyltoluene
Sign Up to like & getrecommendations! Published in 2021 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2021.07.119
Abstract: Abstract Liquid organic hydrogen carrier (LOHC) systems store hydrogen through a catalyst-promoted exothermal hydrogenation reaction and release hydrogen through an endothermal catalytic dehydrogenation reaction. At a given pressure and temperature the amount of releasable hydrogen… read more here.
Keywords: lohc; hydrogen; hydrogenation dehydrogenation; hydrogenation ... See more keywords
Synthesis of Nb-Mo-Si based in situ composite powder by a hydrogenation-dehydrogenation reaction
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DOI: 10.1016/j.matlet.2019.03.134
Abstract: Abstract Nb-Mo-Si based in situ composite powders were fabricated by a hydrogenation-dehydrogenation reaction. The Nb-6Mo-20Si-3Cr alloy ingot was prepared by vacuum arc melting and was composed of a metal solid solution phase and a (Nb,… read more here.
Keywords: dehydrogenation; powder; based situ; hydrogenation dehydrogenation ... See more keywords
Study of Precatalyst Degradation Leading to the Discovery of a New Ru0 Precatalyst for Hydrogenation and Dehydrogenation
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00353
Abstract: The complex Ru-MACHO (1) is a widely used precatalyst for hydrogenation and dehydrogenation reactions under basic conditions. In an attempt to identify the active catalyst form, 1 was reacted with a strong base. The formation… read more here.
Keywords: degradation; dehydrogenation; precatalyst hydrogenation; precatalyst ... See more keywords
Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt02326d
Abstract: Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the… read more here.
Keywords: pincer; dehydrogenation heterocycles; hydrogenation dehydrogenation; complexes based ... See more keywords
Cooperative approaches in catalytic hydrogenation and dehydrogenation.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d1cs01171e
Abstract: Metal-ligand cooperativity (MLC) is an established strategy for developing effective hydrogenation and dehydrogenation catalysts. Metal-metal cooperativity (MMC) in bimetallic complexes is not as well understood, and to date has had limited implementation in (de)hydrogenation. Herein… read more here.
Keywords: hydrogenation; approaches catalytic; hydrogenation dehydrogenation; cooperative approaches ... See more keywords
Study of catalytic hydrogenation and dehydrogenation of 2,3-dimethylindole for hydrogen storage application
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DOI: 10.1039/d1ra01552d
Abstract: The hydrogenation and dehydrogenation of 2,3-dimethylindole was studied. The released hydrogen was in a high purity, detected by DSMS. read more here.
Keywords: hydrogen; dehydrogenation dimethylindole; hydrogenation dehydrogenation;
Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d2cs00093h
Abstract: The emerging field of organometallic catalysis has shifted towards research on Earth-abundant transition metals due to their ready availability, economic advantage, and novel properties. In this case, manganese, the third most abundant transition-metal in the… read more here.
Keywords: hydrogenation dehydrogenation; hydroelementation reactions; dehydrogenation hydroelementation;
Easy hydrogenation and dehydrogenation of a hybrid graphene and hexagonal boron nitride monolayer on platinum
Sign Up to like & getrecommendations! Published in 2021 at "2D Materials"
DOI: 10.1088/2053-1583/abda10
Abstract: Understanding the fundamental steps of adsorption and controlled release of hydrogen in two-dimensional (2D) materials is of relevance for applications in nanoelectronics requiring tuning the physical properties or functionalization of the material, hydrogen storage and… read more here.
Keywords: hydrogen; hydrogenation; boron nitride; hexagonal boron ... See more keywords
Hydrogenation and Dehydrogenation of the Clathrate NaxSi136
Sign Up to like & getrecommendations! Published in 2018 at "Russian Journal of Inorganic Chemistry"
DOI: 10.1134/s0036023618030051
Abstract: Samples of the clathrate NaxSi136 were saturated with hydrogen to 100 atm at 25°C in a Sievertstype apparatus and at pressures of 6 and 28 kbar in lentil-type high-pressure apparatuses at 100 and 250°C. X-ray… read more here.
Keywords: hydrogen; chemistry; clathrate naxsi136; hydrogenation dehydrogenation ... See more keywords