Copper(I)-catalyzed stereoselective hydrogenation of 1,3-diynes and enynes
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DOI: 10.1016/j.tet.2017.05.029
Abstract: A stereoselective hydrogenation of 1,3-diynes with an air-stable copper(I)/N-heterocyclic carbene complex, [IPrCuOH], has been developed. The corresponding products, 1,3-dienes, are obtained in a stereoselective manner depending on their substitution pattern: Diaryl-diynes yield E,E-1,3-dienes, whereas dialkyl-diynes… read more here.
Keywords: stereoselective hydrogenation; hydrogenation; catalyzed stereoselective; hydrogenation diynes ... See more keywords