Base-free CO2 hydrogenation to formic acid over Pd supported on defective carbon nitride modified by microwave and acid treatments
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2021.03.016
Abstract: Abstract Graphitic carbon nitride (g-C3N4) is synthesized via pyrolyzing urea by hybrid microwave annealing (HMA) to support Pd catalyst for direct CO2 hydrogenation to formic acid under a base-free condition. The HMA produces fragmented C3N4… read more here.
Keywords: formic acid; base free; hydrogenation formic; carbon nitride ... See more keywords
Iridium and Ruthenium Complexes of N-Heterocyclic Carbene- and Pyridinol-Derived Chelates as Catalysts for Aqueous Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation: The Role of the Alkali Metal
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.6b00806
Abstract: Hydrogenation reactions can be used to store energy in chemical bonds, and if these reactions are reversible, that energy can be released on demand. Some of the most effective transition metal catalysts for CO2 hydrogenation… read more here.
Keywords: hydrogenation; formic acid; co2 hydrogenation; acid dehydrogenation ... See more keywords
Computational Evidence for Lewis Base-Promoted CO2 Hydrogenation to Formic Acid on Gold Surfaces
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DOI: 10.1021/acscatal.7b00277
Abstract: The mechanism and the effect of Lewis bases in gold-catalyzed CO2 hydrogenation to formic acid were investigated using first principle calculations. The calculations indicate that different types of gold surfaces are all capable of heterolytically… read more here.
Keywords: co2 hydrogenation; gold surfaces; hydrogenation formic; formic acid ... See more keywords