Functionalized Metal-Organic Framework as a Biomimetic Heterogeneous Catalyst for Transfer Hydrogenation of Imines.
Sign Up to like & getrecommendations! Published in 2017 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.7b00562
Abstract: Mimicking a biocatalytic system has been one of the prevalent strategies for the design of novel and efficient chemical transformations. Among the enzyme-catalyzed reactions, the cooperative interplay of Lewis- and Brønsted-acidic functionalities at active sites… read more here.
Keywords: catalyst transfer; hydrogenation imines; heterogeneous catalyst; transfer hydrogenation ... See more keywords
Electrophotocatalytic hydrogenation of imines and reductive functionalization of aryl halides
Sign Up to like & getrecommendations! Published in 2024 at "Nature Communications"
DOI: 10.1038/s41467-024-45015-6
Abstract: Open-shell catalytically active species are widely used in energy-consuming redox reactions, but their excited-state lifetimes are usually short. Here, the authors report a closed-shell thioxanthone-hydrogen anion species generated under electrochemical conditions, which can be photochemically… read more here.
Keywords: hydrogenation imines; aryl halides; hydrogenation; active species ... See more keywords