Comprehensive Study on Ni- or Ir-Based Alloy Catalysts in the Hydrogenation of Olefins and Mechanistic Insight
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DOI: 10.1021/acscatal.0c04615
Abstract: Metal-alloyed atomic catalysts such as single-atom alloys have attracted much attention due to their high atom economy and their unique catalytic properties. Recently, we found that a SiO2-supporte... read more here.
Keywords: comprehensive study; study based; hydrogenation olefins; alloy catalysts ... See more keywords
The Implications of the Brønsted Acidic Properties of Crabtree-Type Catalysts in the Asymmetric Hydrogenation of Olefins
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DOI: 10.1021/jacs.2c07023
Abstract: Chiral iridium complexes derived from Crabtree’s catalyst are highly useful in modern hydrogenations of olefins attributed to high reactivity, stereoselectivity, and stability. Despite that these precatalysts are pH neutral, the reaction mixtures turn acidic under… read more here.
Keywords: hydrogenation olefins; acidic properties; implications nsted; hydrogenation ... See more keywords
Hydrogenation of CO to olefins over a supported iron catalyst on MgAl2O4 spinel: effects of the spinel synthesis method
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DOI: 10.1039/d0ra08387a
Abstract: In the process of CO hydrogenation to olefins by the Fischer–Tropsch synthesis (FTO), the support is a key factor in the activity, selectivity, and thermal and chemical stability of the catalysts, and magnesium aluminate spinel… read more here.
Keywords: mgal2o4; spinel; hydrogenation olefins; catalyst ... See more keywords