Cationic Tantalum Hydrides Catalyze Hydrogenolysis and Alkane Metathesis Reactions of Paraffins and Polyethylene.
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DOI: 10.1021/jacs.2c13610
Abstract: Sulfated aluminum oxide (SAO), a high surface area material containing sulfate anions that behave like weakly coordinating anions, reacts with Ta(═CHtBu)(CH2tBu)3 to form [Ta(CH2tBu)2(O-)2][SAO] (1). Subsequent treatment with H2 forms Ta-H+ sites supported on SAO… read more here.
Keywords: alkane metathesis; hydrogenolysis alkane; alkane; metathesis reactions ... See more keywords