Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts.
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DOI: 10.1002/cssc.202200092
Abstract: 2-Hexanol (2-HOL) is a versatile biomass-derived platform molecule for synthesis of liquid transportation fuels, lubricants or detergents. Herein, a one-step preparation of 2-HOL using 5-hydroxymethylfurfural (HMF) as a substrate was reported for the first time.… read more here.
Keywords: zro2 catalyst; hexanol; hydrogenolysis hydroxymethylfurfural; selective hydrogenolysis ... See more keywords
Tuning the Selectivity of the Hydrogenation/Hydrogenolysis of 5‐Hydroxymethylfurfural under Batch Multiphase and Continuous‐Flow Conditions
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DOI: 10.1002/cssc.202200503
Abstract: Abstract The hydrogenation/hydrogenolysis of 5‐hydroxymethylfurfural (HMF) has been carried out either under single (aqueous) phase or batch multiphase (MP) conditions using mutually immiscible aqueous/hydrocarbon phases, 5 % Ru/C as a catalyst, and both with and without… read more here.
Keywords: batch multiphase; hydrogenation; hydrogenolysis hydroxymethylfurfural; hydrogenation hydrogenolysis ... See more keywords
Insights into the interfacial effects in Cu-Co/CeOx catalysts on hydrogenolysis of 5-hydroxymethylfurfural to biofuel 2,5-dimethylfuran.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2022.01.168
Abstract: The interface site between metal and support possess unique electronic and morphological structure, providing distinct active centers for favorable reaction in catalytic conversion of biomass derivatives to valuable chemicals. In this study, a series of… read more here.
Keywords: interface; coce interface; ceox catalysts; interfacial effects ... See more keywords
Hydrogenolysis of 5-Hydroxymethylfurfural To Produce 2,5-Dimethylfuran over ZrO2 Supported Cu and RuCu Catalysts
Sign Up to like & getrecommendations! Published in 2018 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.8b01234
Abstract: Glucose dehydration to HMF and its hydrogenolysis to DMF, a suitable biofuel, have been studied using the same catalysts for both processes. The 10CuZr catalyst shows the highest HMF yield (25.6%) with an acceptable glucose… read more here.
Keywords: catalyst; hydroxymethylfurfural produce; yield; dmf yield ... See more keywords