Cobalt-Catalyzed Markovnikov Selective Sequential Hydrogenation/Hydrohydrazidation of Aliphatic Terminal Alkynes.
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DOI: 10.1021/jacs.0c07258
Abstract: Here, we reported for the first time a mechanistically distinctive cobalt-catalyzed Markovnikov-type sequential semihydrogenation/hydrohydrazidation of aliphatic terminal alkynes in one pot. A cobalt hydride species was employed as two roles for both a unique metal-catalyzed… read more here.
Keywords: aliphatic terminal; terminal alkynes; cobalt catalyzed; catalyzed markovnikov ... See more keywords